Product ID:CITCOOL 33, 39-333
MSDS Date:11/21/1991
FSC:6850
NIIN:00N046155
MSDS Number: BTXPS

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 318-491-6215;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

1.1 G/KG.

RTECS: 9999999ZZ

Fraction By Weight: <.015%

OSHA PEL N/K

ACGIH TLV: N/K

BACTERIACIDE

OSHA PEL N/K

ACGIH TLV: N/K

FUNGICIDE

OSHA PEL N/K

ACGIH TLV: N/K

30 G/KG.

Fraction By Weight: <.02%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: >50%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANOL, 2,2'-IMINODI-; (DIETHANOLAMINE) (SARA III). LD50

CAS: 111-42-2

RTECS: KL2975000

Fraction By Weight: 10-20%

OSHA PEL 3 PPM

ACGIH TLV: 3 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

RUST INHIBITOR

Fraction By Weight: 10-15%

OSHA PEL N/K

ACGIH TLV: N/K

>5 G/KG.

CAS: 9038-95-3

Fraction By Weight: 7-14%

OSHA PEL N/K

ACGIH TLV: N/K

DISODIUM 2,5-DIMERCAPTOTHIADIAZOLE; (SODIUM

CAS: 55906-42-8

Fraction By Weight: SEE ING

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: SLIGHT PULMONARY
AND MUCOUS MEMBRANE IRRITANT. SKIN: MILD IRRITATION. EYE: BLURRED
VISION AND BLINDNESS FOLLOWING INGESTION HAVE BEEN RECORDED,
ASSOCIATED WITH CNS DEPRESSION AND CO MA. INGESTION: PRODUCES
ALCOHOL-LIKE INTOXICATION, PROGRESSING TO DIZZINESS, VOMITING, COMA
AND DEATH, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEALTH HAZARDS: UNLESS TREATED IMMEDIATELY.
INJECTION: IRRITATION, ERYTHEMA, EDEMA. CHRONIC: CHRONIC EXPOSURE
RARE IN INDUSTRY, UNLESS EXPOSURE TO REPEATED, MASSIVE VAPOR
CONCENTRATIONS, FROM HEATING OF FLUID ABOVE 100C.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHAL:REMOVE VICTIM FROM EXPOS. SEEK MED AID. LEND RESP
SUPPORT. SKIN: WASH IMMED W/SOAP & WATER. SEEK MED AID. REMOVE
CONTAMD CLTHG. EYES: IMMED FLUSH W/WATER FOR AT LST 15 MINS.
CONTINUE TREATMENT O N WAY TO PHYS. INGEST: SEEK IMMED MED AID.
INJECT: PRESENTS MED EMER, SEEK MED AID. NOTES TO MD: FOLLOWING
INGEST, IMMED TREATMENT IS CRUCIAL. PRINCIPLE EFTS OF INGEST/ACUTE
OVEREXP ARE KIDNEY(SUPDAT)

Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT FLAMMABLE.

Spill Release Procedures:DIKE FOR LATER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE BELOW 150F. DO NOT APPLY HEAT OR
FLAME TO CONTAINER. KEEP SEPARATE FROM STRONG OXIDIZING AGENTS.
Other Precautions:CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL
AUTHORITIES BEFORE REUSING, RECONDITIONING, RECLAIMING, RECYCLING
OR DISPOSING OF EMPTY CONTAINERS AND/OR WASTE RESIDUES OF PRODUCT.

Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC RESPIRATOR ABOVE
TLV.
Ventilation:USE LOCAL AND GENERAL VENTILATION.
Protective Gloves:POLYMER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKER GOGGLES
Other Protective Equipment:NONE.
Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PROCEDURE. WASH
EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER.
Supplemental Safety and Health
SPECIFIC GRAVITY: 1.07 (60/60F) (H2O=1). FIRST AID PROCEDURES: EFFECTS
AND METABOLIC ACIDOSIS. IN SEVERE CASES HEMODIALYSIS MAY BE
CONSIDERED. VAPORS OR FUMES MAY CAUSE TRANSIENT DERMAL, EYE AND
RESPI RATORY IRRITATION.

HCC:B3
Spec Gravity:SUPP DATA
pH:9.5
Solubility in Water:SOLUBLE
Appearance and Odor:BLUE LIQUID, BLAND ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS OR ACID, SUCH AS NITRIC OR SULFURIC ACID, OR COMPOUNDS
WITH REACTIVE HYDROXY FUNCTIONS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE (CARBON MONOXIDE UNDER
INCOMPLETE COMBUSTION). OXIDES OF NITROGEN UNDER FIRE CONDITIONS.

Waste Disposal Methods:MAY BE DISP OF THRU CNTRLD INCIN OR LAND BURIAL
IF IN COMPLIANCE W/FED, ST & LOC REGS. IT IS RESPONSIBILITY OF USER
TO DETERM IF MATL IS HAZ WASTE AT TIME OF DISP. CHEMTREC/RCRA EMER
HOTLINE NUMBER: 8 00-424-9346. DISP I/A/W FED, ST, & LOC REGS.

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particular situation.